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51.
We present experiments showing that the lower oceanic crust should melt efficiently and quickly when heated by hot ascending magmas. Average plagioclase–olivine and plagioclase–augite pairs from the lower crust at the Southwest Indian Ridge have melt–mineral saturation boundaries at 1,190 and 1,154°C, respectively, and melt rapidly (>0.01 mm/h) at 50°C or more above these temperatures. Melting experiments performed on olivine–plagioclase and augite–plagioclase mineral pairs from actual oceanic lower crustal rock samples and under conditions applicable to a MOR setting (1,220–1,330°C, 1 atm, quartz–fayalite–magnetite oxygen buffer, 0.25–24 h) indicate that the resulting disequilibrium melts are linear mixes of the mineral compositions. The rates of melting are slower than the rate of heat-diffusion into a sample and are approximated as:
Our results indicate that great care must be taken in backward models using basalt chemistry alone to explore mantle-melting processes, assuming only crystallization and fractionation during ascent, as partial melts may mix with intruded hot magma.  相似文献   
52.
The movement of magma through the shallow crust and the impact of subsurface sill complexes on the hydrocarbon systems of prospective sedimentary basins has long been an area of interest and debate. Based on 3D seismic reflection and well data, we present a regional analysis of the emplacement and magmatic plumbing system of the Palaeogene Faroe‐Shetland Sill Complex (FSSC), which is intruded into the Mesozoic and Cenozoic sequences of the Faroe‐Shetland Basin (FSB). Identification of magma flow directions through detailed seismic interpretation of approximately 100 sills indicates that the main magma input zones into the FSB were controlled primarily by the NE–SW basin structure that compartmentalise the FSB into its constituent sub‐basins. An analysis of well data shows that potentially up to 88% of sills in the FSSC are <40 m in thickness, and thus below the vertical resolution limit of seismic data at depths at which most sills occur. This resolution limitation suggests that caution needs to be exercised when interpreting magmatic systems from seismic data alone, as a large amount of intrusive material could potentially be missed. The interaction of the FSSC with the petroleum systems of the FSB is not well understood. Given the close association between the FSSC and potential petroleum migration routes into some of the oil/gas fields (e.g. Tormore), the role the intrusions may have played in compartmentalisation of basin fill needs to be taken fully into account to further unlock the future petroleum potential of the FSB.  相似文献   
53.
Demersal rockfish are the only fish species that have been found dead in significant numbers after major oil spills, but the link between oil exposure and effect has not been well established. After the 1989 Exxon Valdez oil spill in Prince William Sound, Alaska, several species of rockfish (Sebastes spp.) from oiled and reference sites were analyzed for hydrocarbon metabolites in bile (1989-1991) and for microscopic lesions (1990 and 1991). Biliary hydrocarbons consistent with exposure to Exxon Valdez oil were elevated in 1989, but not in 1990 or 1991. Significant microscopic findings included pigmented macrophage aggregates and hepatic megalocytosis, fibrosis, and lipid accumulation. Site differences in microscopic findings were significant with respect to previous oil exposure in 1991 (P=0.038), but not in 1990. However, differences in microscopic findings were highly significant with respect to age and species in both years (P<0.001). We conclude that demersal rockfish were exposed to Exxon Valdez oil in 1989, but differences in microscopic changes in 1990 and 1991 were related more to age and species differences than to previous oil exposure.  相似文献   
54.
Hurricanes David (August 29–30, 1979) and Frederick (September 2–5, 1979) caused major flooding of the Rio de La Plata in northern Puerto Rico. A thin mud layer was deposited across the narrow insular shelf adjacent to the river mouth. Within 5 months, fair-weather shelf-winnowing processes moved the mud layer entirely from the shelf, 0.5 to 2 km to the shelf break at the 50-m contour and beyond. The process of mud movement is termed “mud hopping.”  相似文献   
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56.
Located in northern Québec, the Lac Shortt Mine was a small gold mine consisting of a thin subvertical orebody which was mined in three main phases. High stress and rockbursting conditions were experienced when ore was extracted in the upper zone between the surface and a depth of 500 metres during the first two phases of mining. Severe rockbursts were experienced in late 1989 near the shaft and in the footwall development following a deepening of the mine shaft to a depth of 830 m and partial development of footwall drift access for the third phase of mining (the mining of the lower zone starting at a depth of 830 m moving upward toward a depth of 500 m). A 16-channel Electrolab MP250 microseismic system, with a Queen's University Full-Waveform piggy-back system, was installed underground at the site due to these problems.It was expected that the thinning sill would be subjected to an ever-increasing load as the thickness of the 500 m sill pillar decreased in the face of the mining excavation from below. A monitoring program consisting of the microseismic monitoring system, a range of conventional geomechanics monitoring tools as well as the undertaking of periodic seismic tomography surveys to assess the ongoing state of stress and rock mass condition within the sill was therefore warranted.The anomalously high-magnitude stress field and the brittle rockmass created a situation in which rockmass failure was common and violent. In the creation and thinning of the sill pillar, the location of banded microseismic activity was crucial in tracing rockmass failure and the associated ground control problems. Reliable source-location determination enabled the identification of areas of stress increase. The movement of the rockmass failure front could be followed, and was responsible for stope dilution, footwall and orebody development deterioration, and caving.Source-mechanism analyses gave accurate double-couple solutions for approximately forty percent of these events having at least ten recognizable polarities. Results suggested movement along vertical north-south striking or vertical east-west striking features. Underground observation of damaged access points showed that vertical north-south striking joints were experiencing failure.The microseismic activity, which was consistently concentrated close to the southwest and northeast corners of current production stopes, could be explained by a stress field oriented obliquely to the strike of the orebody, as measured prior to shrinkage of the sill pillar byin situ stress measurements and observed borehole overbreaks. The orientations of theP andT axes for the microseismic activity further confirmed that the stress field oriented obliquely to strike.While an increase in compressional-wave velocity of 2.3 percent, corresponding to a measured stress increase of approximately 10 MPa could be measured by repeated tomographic surveys, it was relatively small and only a factor of two or so above the velocity measured uncertainty. The relative insensitivity of thein situ rock mass modulus to the applied stress is believed to be largely due to the rockmass discontinuities being relatively closed prior to stress increase, as substantiated by the small deformations seen by the extensometer and borehole camera. This situation existed because of the very high pre-mining stress level.The experimental demonstration that the rock could not absorb substantially increased load through the mechanism of discontinuity closure or tightening (which would be reflected in the modulus) may be evidence in itself of potentially burst-prone ground, such as encountered at Lac Shortt.  相似文献   
57.
Changes in phytoplankton composition and degradation of particulate organic matter (POM) in the northwestern Mediterranean Sea were studied using time-series sediment trap samples collected during the spring of 2003 at the DYFAMED station. Lipid biomarkers (pigments, fatty acids, sterols, acyclic isoprenoids, alkenones and n-alkanols) were used to identify the main contributors to the POM produced during two phytoplankton blooms, while the effects of photooxidation, autoxidation and biodegradation were differentiated using characteristic lipid degradation products. Traps collected material corresponding to pre-bloom, bloom and post-bloom periods. Pigment analyses in the integrated (0-200 m) water column samples indicated that diatoms dominated the initial stages of the bloom event, with smaller amounts of haptophytes and pelagophytes. During the second part of bloom event there was a switch to haptophyte dominance with significant contributions from diatoms and pelagophytes, and an increased contribution from cryptophytes. Fatty acid distributions in the trap samples reflected contributions from marine bacteria, phytoplankton and zooplankton. Photooxidation and autoxidation products of monounsaturated oleic, cis-vaccenic and palmitoleic acids were detected along with photooxidation products from the chlorophyll side-chain. The relatively good correlation between the variation of U37K′ index and specific phytol autoxidation product percentage allowed us to attribute the alterations of U37K′ observed during the pre-bloom period and in the deeper traps to the involvement of selective autoxidative degradation processes. A variety of sterol oxidation products formed by biohydrogenation, autoxidation and photooxidation were detected. Sterol degradation products appeared to be less suited than oxidation products of monounsaturated fatty acids for the precise monitoring of the degradation state of POM, but their stable functionalized cyclic structure constitutes a useful tool to estimate the part played by biotic and abiotic processes. In these waters, biotic degradation generally predominates, but abiotic degradation is not negligible and, as expected, the extent of biotic degradation increases with depth. To obtain a more complete picture of POM degradation, the use of a pool of lipid degradation products (i.e. from unsaturated fatty acids, the phytyl side-chain and sterols) should be employed.  相似文献   
58.
European Venus Explorer (EVE): an in-situ mission to Venus   总被引:1,自引:0,他引:1  
The European Venus Explorer (EVE) mission was proposed to the European Space Agency in 2007, as an M-class mission under the Cosmic Vision Programme. Although it has not been chosen in the 2007 selection round for programmatic reasons, the EVE mission may serve as a useful reference point for future missions, so it is described here. It consists of one balloon platform floating at an altitude of 50–60 km, one descent probe provided by Russia, and an orbiter with a polar orbit which will relay data from the balloon and descent probe, and perform science observations. The balloon type preferred for scientific goals is one which oscillates in altitude through the cloud deck. To achieve this flight profile, the balloon envelope contains a phase change fluid, which results in a flight profile which oscillates in height. The nominal balloon lifetime is 7 days—enough for one full circumnavigation of the planet. The descent probe’s fall through the atmosphere takes 60 min, followed by 30 min of operation on the surface. The key measurement objectives of EVE are: (1) in situ measurement from the balloon of noble gas abundances and stable isotope ratios, to study the record of the evolution of Venus; (2) in situ balloon-borne measurement of cloud particle and gas composition, and their spatial variation, to understand the complex cloud-level chemistry; (3) in situ measurements of environmental parameters and winds (from tracking of the balloon) for one rotation around the planet, to understand atmospheric dynamics and radiative balance in this crucial region. The portfolio of key measurements is complemented by the Russian descent probe, which enables the investigation of the deep atmosphere and surface.  相似文献   
59.
We have investigated the distribution and isotopic composition of nitrogen and noble gases, and the Ar-Ar chronology of the Bencubbin meteorite. Gases were extracted from different lithologies by both stepwise heating and vacuum crushing. Significant amounts of gases were found to be trapped within vesicles present in silicate clasts. Results indicate a global redistribution of volatile elements during a shock event caused by an impactor that collided with a planetary regolith. A transient atmosphere was created that interacted with partially or totally melted silicates and metal clasts. This atmosphere contained 15N-rich nitrogen with a pressure ?3 × 105 hPa, noble gases, and probably, although not analyzed here, other volatile species. Nitrogen and noble gases were re-distributed among bubbles, metal, and partly or totally melted silicates, according to their partition coefficients among these different phases. The occurrence of N2 trapped in vesicles and dissolved in silicates indicates that the oxygen fugacity (fO2) was greater than the iron-wüstite buffer during the shock event. Ar-Ar dating of Bencubbin glass gives an age of 4.20 ± 0.05 Ga, which probably dates this impact event. The cosmic-ray exposure age is estimated at ∼40 Ma with two different methods. Noble gases present isotopic signatures similar to those of “phase Q” (the major host of noble gases trapped in chondrites) but elemental patterns enriched in light noble gases (He, Ne and Ar) relative to Kr and Xe, normalized to the phase Q composition. Nitrogen isotopic data together with 40Ar/36Ar ratios indicate mixing between a 15N-rich component (δ15N = +1000‰), terrestrial N, and an isotopically normal, chondritic N.Bencubbin and related 15N-rich meteorites of the CR clan do not show stable isotope (H and C) anomalies, precluding contribution of a nucleosynthetic component as the source of 15N enrichments. This leaves two possibilities, trapping of an ancient, highly fractionated atmosphere, or degassing of a primitive, isotopically unequilibrated, nitrogen component. Although the first possibility cannot be excluded, we favor the contribution of primitive material in the light of the recent finding of extremely 15N-rich anhydrous clasts in the CB/CH Isheyevo meteorite. This unequilibrated material, probably carried by the impactor, could have been insoluble organic matter extremely rich in 15N and hosting isotopically Q-like noble gases, possibly from the outer solar system.  相似文献   
60.
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